CFRP电流辅助铆接的连接域热响应建模与验证

钛合金铆钉变形时易不均匀、易开裂,在碳纤维增强树脂基复合材料（CFRP）铆接过程中引入脉冲电流作用,软化铆钉并改善其塑性。研究了连接域内的热响应机制与温度场分布,基于能量守恒、焦耳热定律、热传导定律构建了静态焦耳热模型表征稳态换热铆接工况下的CFRP温度,考虑铆接过程电流波动、温度分布不均和热区域分散性建立了动态温度场模型预测铆接过程温升。结果表明：CFRP孔周一定辐射半径范围处温度与钉中心温度线性相关,模型准确模拟出了40 s内的过程温度。静态模型在11%误差以内精准预测了中心饱和温度,动态模型模拟的温升趋势与实测温度值吻合较好。热量传递的滞后性使得动态模型对快速温升时的温度预测存在误差,该误差随电流密度变大而增加,最大达17.15%。接头损伤评估表明过程温度控制在150℃内时可获得质量合格的铆接接头。     

Wetting behavior of AgCu-4.5Ti filler reinforced by carbon nanotubes on C/C composite

The effect of Carbon Nanotubes (CNTs) content on the wettability of AgCu-4.5Ti + x CNTs (wt%) composite filler alloys on C/C composite was investigated. The results show that the added CNTs reacted with element Ti in the filler and produced the dispersed fine in situ synthesized TiC particles, which increased the consumption of element Ti and provided the nucleus for the growth of Ti-Cu compounds simultaneously. The above effects of introducing CNTs, inhibited the formation of Ti-Cu compounds, also changed the distribution of compounds, which dramatically influenced the interfacial microstructure and characteristics of wetting behavior. The increase of CNTs content refined and dispersed coarse Ti-Cu compounds, decreased the initial spreading temperature, and improved the wettability, but high content of CNTs (more than 0.3wt%) decreased the wettability of the filler alloy. The wetting interfacial microstructure of corresponding composite filler alloys were analyzed by Scanning Electron Microscope (SEM), Energy Dispersive X-ray Spectrometer (EDS) and Transmission Electron Microscope (TEM), which consisted of TiC, TiCu, TiCu₂ and TiCu₄ compound. The typical wetting behavior of AgCu-4.5Ti + 0.3wt% CNTs composite filler on C/C composite was divided into four stages. The effect mechanism of CNTs content on the wetting behavior was proposed.     

Laser joining of CFRTP to titanium alloy via laser surface texturing

Grid pattern was textured on Ti-6Al-4V alloy (TC4) substrate surface by nanosecond laser system. Laser joining of carbon fiber reinforced thermoplastic composite (CFRTP) to TC4 joints were performed, and the effect of texture grid depth was investigated. The contact angle of molten CFRTP on textured TC4 surface was measured and the tensile-shear force was tested. The fracture surface and interface morphology were observed. The results indicated that the wettability of molten CFRTP on TC4 surface improved remarkably after laser textured TC4. Shear force of CFRTP/TC4 joints was increased by 156% after laser textured TC4 surface. When the depth of grid was deeper than 100 μm, contact angle increased and incomplete filling of molten CFRTP in grid occurred, the shear force thus decreased gradually. Resin-carbon fibers mixture was adhered on the fracture surface of TC4, and the variation tendency of adhesion ratio was consistent with that of shear force. TC4 matrix was exfoliated from substrate and adhered at the fracture surface of CFRTP, indicating stronger mechanical interlocking occurred at the joining interface after laser textured TC4 surface. Beside mechanical interlocking, compound layer consisted of CTi_0.42V_1.58 carburization phase was also confirmed at interface, suggesting that chemical bonding also occurred at the joining interface.     

大尺寸CFRP固体火箭发动机壳体湿法缠绕用树脂配方研制

针对大尺寸炭纤维增强复合材料（CFRP）固体火箭发动机壳体的制备要求,研制了一种具 有良好粘度－温度及粘度－时间特性的炭纤维复合材料湿法缠绕成型树脂配方A。采用差示 扫描量热法（DSC）、傅立叶红外光谱（FT-IR）等分析技术对树脂基体的固化反应进行了系 统地研究,并测试了配方的粘度、力学性能及容器爆破强度。结果表明,该树脂配方A的反应 表观活化能为41.71 kJ／moL,室温下粘度低（≤0.5390 Pa·s）,适用期较长 （＞48 h ） ,不仅完全满足大尺寸CFRP固体火箭发动机壳体的湿法缠绕成型工艺要求,而且其树脂基体 及其炭纤维复合材料表现出优良的力学性能。炭纤维复合材料界面粘接良好,缠绕的
Φ150 mm容器的PV／W均大于48 km,纤维强度转化率达到89.0％以上。
     

碳纤维电阻率的评价表征

通过对QJ3074-1998中的测试原理和测试夹具的改进,提高了四探针法线材电阻率测试仪的测试精度并拓宽了测试范围,获得了试验验证.通过试样长度对测试结果的影响及试验条件对测试结果的影响等试验,系统评价表征了各种碳纤维的电阻率,为建立碳纤维电阻率测试方法标准奠定了重要的技术和数据基础.     

壁面厚度随机度对闭孔Voronoi泡沫材料弹性性能的影响

基于闭孔Voronoi随机模型,通过引入壁面厚度随机度,研究了壁面厚度不均匀性对各向同性和各向异性闭孔泡沫弹性性能的影响,并讨论了壁面厚度随机度与模型随机度共同作用下的影响效果.结果表明,壁面厚度随机度对各向同性和各向异性弹性模量均起减小的作用,且其在各向同性时的影响效果要低于模型随机度的影响,而在各向异性情况下则要高于模型随机度的影响.但是,壁面厚度随机度对闭孔泡沫的泊松比影响却很小.      

碳纤维复合材料低温热导率的实用计算方法

探讨和验证了碳纤维复合材料（ＣＦＲＰ）低温传热及低温热导率的一般规律、影响因素和计算方法;在分析讨论的基础上,总结归纳了热导率计算方法,并将计算结果与测试结果进行了比对,为设计、推算ＣＦＲＰ材料的低温热导率提出了实用的计算方法。     

用CT图像分析C／C复合材料的内部缺陷

总结了不同类型三向增强Ｃ／Ｃ复合材料ＣＴ检测图像及其对应的内部缺陷,结果表明：ＣＴ技术主要缺陷区与正常区存在的密度差异,对Ｃ／Ｃ复合材料内部进行质量检测,但在某些特定条件下,相同种类的缺陷可能表现出不同的ＣＴ图像,不同种类缺陷可能产生类似的ＣＴ图像,缺陷类型的判定必须与其它检测手段相结合才可确定,ＣＴ检测也有可能漏检部分缺陷。     

碳纤维沥青裂解碳涂层研究

研究了沥青裂解法在碳纤维表面涂覆均匀碳涂层的工艺,并探讨了不同溶剂,不同浓度的涂层溶液对纤维表面形貌和纤维强度的影响。     

粒子辐照对碳纤维复合材料力学性能影响

对部分碳纤维复合材料粒子辐照前后的力学性能进行了测试和比对,分析了粒子辐照对该材料力学性能影响的部分机理和一些变化规律,进行了微观理论上的探讨。